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This protocol also worked well with coumarin-3-carboxylic acids to unveil a rare instance of a catalyst-free tandem alkylation/decarboxylation reaction with conservation of the double bond. This protocol employs tert-butyl hydroperoxide as the sole reagent of the reaction to combine coumarins and ethers in reasonable yields under metal- and solvent-free reaction conditions.

Vanessa mata boa sorte torrents page 1 of 82.ДЄ regioselective direct alkylation of coumarins at C-3 via cross-dehydrogenative coupling of unactivated Csp 2вЂ“Csp 3 bonds is developed.

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